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Technical Paper

Speciation of Evaporative Emissions from Plastic Fuel Tanks

1998-05-04
981376
Until now no results have been available regarding the composition of evaporative emissions in a SHED test. In particular, for alcohol containing fuels, it is important to assess the relative percentage of alcohols and hydrocarbons in view of their different environmental impacts. This paper presents the results of a study conducted to determine the composition of the emissions from a number of multilayer coextruded plastic fuel tanks soaked in IE10 and CM15 test fuels. These emissions were analyzed for composition using a gas chromatography analytical method which employs a vapor trap and desorb sampling technique. In the case of CM15, methanol was found to account for as much as 50% of the overall evaporative emissions. This speciation method also allows estimation of how leakage and permeation contribute separately to the overall emissions.
Technical Paper

Making the Case for a Next Generation Automotive Electrical System

1998-10-19
98C006
Introduction of an array of new electrical and electronic features into future vehicles is generating vehicle electrical power requirements that exceed the capabilities of today's 14 volt electrical systems. In the near term (5 to 10 years), the existing 14V system will be marginally capable of supporting the expected additional loads with escalating costs for the associated charging system. However, significant increases in vehicle functional content are expected as future requirements to meet longer-term (beyond 10 years) needs in the areas of emission control, fuel economy, safety, and passenger comfort. A higher voltage electrical system will be required to meet these future requirements. This paper explores the functional needs that will mandate a higher voltage system and the benefits derivable from its implementation.
Technical Paper

The Occurrence of Flash Boiling in a Port Injected Gasoline Engine

1998-10-19
982522
The occurrence of flash boiling in the fuel spray of a Port Fuel Injected (PFI) spark ignition engine has been observed and photographed during normal automotive vehicle operating conditions. The flash boiling of the PFI spray has a dramatic affect on the fuel spray characteristics such as droplet size and spray cone angle which can affect engine transient response, intake valve temperature and possibly hydrocarbon emissions. A new method of correlating the spray behavior using the equilibrium vapor/liquid (V/L) volume ratio of the fuel at the measured fuel temperature and manifold pressure is introduced.
Technical Paper

Regimes of Premixed Turbulent Combustion and Misfire Modeling in SI Engines

1998-10-19
982611
A review of flame kernel growth in SI engines and the regimes of premixed turbulent combustion showed that a misfire model based on regimes of premixed turbulent combustion was warranted[1]. The present study will further validate the misfire model and show that it has captured the dominating physics and avoided extremely complex, yet inefficient, models. Results showed that regimes of turbulent combustion could, indeed, be used for a concept-simple model to predict misfire limits in SI engines. Just as importantly, the entire regimes of premixed turbulent combustion in SI engines were also mapped out with the model.
Technical Paper

Intra-Parcel Collision Model for Diesel Spray Simulations

2008-10-06
2008-01-2426
Multidimensional models that are used for engine computations must include spray sub-models when the fuel is injected into the cylinder in liquid form. One of these spray sub-models is the droplet interaction model, which is separated into two parts: first, calculation of a collision rate between drops, and second, calculation of the outcome once a collision has occurred. This paper focuses on the problem of calculating the collision rate between drops accurately. Computing the collision rate between drops or particles when they are non-uniformly distributed and sharp gradients are present in their distribution is a challenging task. Traditionally the collisions between parcels of drops have been computed using the same spatial grid as is used for the Eulerian gas-phase calculations. Recently it has been proposed to use a secondary grid for the collision rate calculation that is independent of the gas-phase grid, as is done in the NTC collision algorithm.
Technical Paper

Research Application of DFSS: Study of the Impact of Accelerated Aging and Recovery on Low-Rh Three-Way Catalyst Activity for Catalyst Monitoring

2010-04-12
2010-01-0702
Robust on-board diagnosis of emission catalyst performance requires the development of artificially damaged "threshold" catalysts that accurately mimic the performance of damaged catalysts in customer use. The threshold catalysts are used by emissions calibrators to determine fore-aft exhaust oxygen sensor responses that indicate catalyst failure. Rather than rely on traditional trial-and-error processes to generate threshold catalysts, we have used a DFSS (Design For Six-Sigma) approach that explores, at a research level, the relationship between oxygen storage capacity (OSC) of the catalyst (i.e., the fundamental property dictating the response of the aft oxygen sensor) and key process input variables: high-temperature exposure, phosphorus poisoning, and catalyst "recovery."
Technical Paper

Modeling Water Condensation in Exhaust A/T Devices

2010-04-12
2010-01-0885
Ignoring the impact of water condensation leads to incorrect temperature simulation during cold start, and this can lead to questions being raised about the overall accuracy of aftertreatment simulation tools for both temperature and emission predictions. This report provides a mathematical model to simulate the condensation and evaporation of water in exhaust after-treatment devices. The simulation results are compared with experimental data. Simulation results show that the temperature profiles obtained using the condensation model are more accurate than the profiles obtained without using the condensation model. The model will be very useful in addressing questions that concern the accuracy of the simulation tool during cold-start and heating up of catalysts, which accounts for the conditions where tailpipe emission issues are most significant.
Technical Paper

Exhaust Gas Temperature Determination with HEGO Parameters

2010-04-12
2010-01-1303
Exhaust gas temperature is often measured with a device such as thermocouple or RTD (Resistance Temperature Detector). An alternative method to determine the gas temperature would be to use an existing gas sensor heating mechanism to perform as a temperature sensor. A planar type FLOH (Fast Light Off HEGO-Heated Exhausted Gas Oxygen) sensor under transient vehicle speed/load conditions is suited to this function and was modeled to predict the exhaust gas temperature. The numerical input to the model includes exhaust flow rate, heater voltage, and heater current. Laboratory experiments have been performed to produce an equation relating the resistance of the heater and the temperature of the sensor (heater), which provides a method to indirectly determine HEGO sensor temperature.
Technical Paper

The Development of Advanced Urea-SCR Systems for Tier 2 Bin 5 and Beyond Diesel Vehicles

2010-04-12
2010-01-1183
An advanced diesel aftertreatment system utilizing Selective Catalytic Reduction (SCR) with urea for lean nitrogen oxides (NOx) control was tested on a 2.7L V6 Land Rover vehicle to demonstrate the capability of achieving Tier 2 Bin 5 and lower emission standards for light-duty trucks. SCR washcoat was applied to a diesel particulate filter (DPF) to perform NOx and particulate reduction simultaneously. Advanced SCR systems employed both traditional SCR catalysts and SCR-coated filters (SCRF) to improve the NOx reduction efficiency. The engine-out NOx level was adjusted by modifying the EGR (Exhaust Gas Recirculation) calibration. Cold start NOx performance was improved by SCR warm-up strategy and urea over injection. This study showed the advanced SCR system could tolerate higher NH₃ storage in the SCR catalyst, resulting in overall higher NOx conversion on the FTP-75 test cycle.
Technical Paper

Deactivation of Cu/Zeolite SCR Catalyst under Lean-Rich Aging Conditions

2010-04-12
2010-01-1180
A lean-rich hydrothermal aging was used to study the deactivation of Cu-zeolite SCR catalyst that has enhanced stability. Impact of DOC upstream on the SCR catalyst during the lean-rich aging was also investigated. The LR hydrothermal aging was conducted with the presence of hydrocarbon, CO and H₂ at different O₂ levels. It was found that the SCR catalyst was active for the oxidation of CO, H₂ and hydrocarbon, resulting in significant exotherm across the catalyst. In addition to hydrothermal aging, reductive aging, especially the presence of H₂ in the aging gas stream without O₂ presence during the L-R aging, might also contribute to the Cu/zeolite SCR catalyst deactivation. The impacts of DOC upstream on Cu/zeolite SCR catalysts depended on the aging temperatures. At lower aging temperature, the uncompleted oxidation of hydrocarbon and CO on the DOC might cause steam reforming and water-gas shift reactions on the DOC to form reductive gas stream.
Technical Paper

Diesel EGR Cooler Fouling with Ni-Fe-Cr-Al DPF at Freeway Cruise

2010-10-05
2010-01-1955
This study investigates the effect of diesel particulate filters (DPF) on the performance of exhaust gas recirculation (EGR) coolers. EGR coolers were tested with and without the use of a DPF and their measured performances were compared. The exhaust gas was filtered using a Ni-Fe-Cr-Al metallic foam wall flow diesel particulate filter. The DPFs used in this investigation had very low Space Velocity (SV) characteristics in order to minimize the effect of filtration on the pressure drop. Two different measurement methods were employed to determine particulate matter (PM) emission levels at locations before and after the DPF. The first method involved the collection of PM on quartz filters followed by thermal analysis of the filters to monitor the removal of soot, semi-volatile organics, and sulfate across the DPF. The second method measured the time resolved PM mass in the exhaust with a Dekati Mass Monitor.
Technical Paper

Engine Reliability Through Infant Mortality Mitigation: Literature Review

2010-10-06
2010-36-0049
Internal combustion engines are designed to meet the high power, low fuel consumption and also, low exhaust emissions. The engine running conditions is valid the concept that, the expectative is very high because of the variety of operating conditions like cold start, frequent start and stop, time high speed and load, traditional gasoline, mix of gasoline and alcohol and finally, alcohol fuel only. Considering such demand, this paper explains the relationship between the reliability bathtub curve, specifically the "Infant Mortality" portion. The bathtub curve describes failure rate as a function of time. The "Infant Mortality" portion of the curve is the initial section for which the failure (death) rate decreases with time (age). In general, these problems are related to manufacturing aspects or poor design definitions. With development of technology, hard failures, the ones that cause dependability, are becoming rare.
Technical Paper

Internal combustion engine calibration teaching by Stand Alone System.

2010-10-06
2010-36-0346
Internal combustion engine calibration teaching by Stand Alone System. This paper illustrates a teaching methodology for technical students of internal combustion engine calibration, by stand alone engine control unit with variable ignition and fuel injection time. Using a system named HIS (Stand alone Electronic Control Unit), to change the engine parameters, as fuel injection time and ignition time, the students can optimize fuel consumption, performance and exhaust emission. The tests are developed using the DOE (design of experiments) technique of artificial intelligence.
Technical Paper

Gear Lever Sound Quality Evaluation

2010-10-06
2010-36-0369
Vehicle sound quality has become lately one of the main topics of study in the automotive industry which is associated with the quality of the product. Into the automotive development the static operational sound quality is one of the attributes that is considered. The sounds produced through the manipulation of items like the doors and interior components (windows, seats, safety belts, windshield wipers, and others) generated for safety and warning purposes are items related to the vehicle quality for customers. Those sounds based on relative level of intensity, duration, harmony and degree of contribution are elements that the customer will retain in mind, an overall quality impression. The sound produced during gear lever manipulation is important to the customer in order that the event should transmit low intensity and robust and soft impression.
Technical Paper

Development of an Al2O3/ZrO2-Composite High-Accuracy NOx Sensor

2010-04-12
2010-01-0041
In 1999, the first generation NOx sensor from NGK Spark Plug, Co., Ltd. was commercialized for use in gasoline LNT NOx after-treatment systems [ 1 ]. Since then, as emissions regulations and OBD requirements have become more stringent, the demand for a high-accuracy NOx sensor with fast light-off has increased, particularly for diesel after-treatment systems. To meet such market demands, NGK Spark Plug, Co., Ltd. has developed, in collaboration with Ford Motor Company, a second generation NOx sensor.
Technical Paper

An Assessment of Vehicle Side-Window Defrosting and Demisting Process

2001-03-05
2001-01-0289
The thermal comfort of passengers within a vehicle is often the main objective for the climate control engineer; however, the need to maintain adequate visibility through the front and side windows of a vehicle is a critical aspect of safe driving. This paper compares the performance of the side window defrosting and demisting mechanism of several current model vehicles. The study highlights the drawbacks of current designs and points the way to improved passive defrosting mechanisms. The investigation is experimental and computational. The experiments are carried out using full-scale current vehicle models. The computational study, which is validated by the experiments, is used to perform parametric investigation into the side window defrosters performance. The results show that the current designs of the side-defroster nozzles give maximum airflow rates in the vicinity of the lower part of the window, which yields unsatisfactory visibility.
Technical Paper

Development of a Desulfurization Strategy for a NOx Adsorber Catalyst System

2001-03-05
2001-01-0510
The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.
Technical Paper

Comparison of Performance between Several Vehicle Windshield Defrosting and Demisting Mechanisms

2001-03-05
2001-01-0582
The safety and comfort aspects of passenger cars are significant sales argument and have become a topic of rising importance during the development process of a new car. The objective of this study is to compare the performance of several current model vehicles, highlight the drawbacks of current defrosting/demisting systems and point the way to improved passive mechanisms. The investigation is experimental. The experiments are carried out using full-scale current vehicle models. The results show that the current designs of the defroster nozzle give maximum airflow rates in the vicinity of the lower part of the windshield, which decrease gradually towards the upper parts of the windshield. This hinders and limits the vision of the driver, particularly at the top of the windshield, which can be uncomfortable and indeed dangerous.
Technical Paper

Estimating Real Time Diurnal Permeation from Constant Temperature Measurements

2001-03-05
2001-01-0730
Using the results of Constant Temperature (CT) Permeation Measurements to estimate Real Time Diurnal (RTD) permeation emissions has a number of practical advantages. In particular, Constant Temperature measurements are easier to set up and control in a laboratory environment, and Constant Temperature measurements provide for data checks using simple self-consistency tests that are not possible with Real Time Diurnal measurements. Furthermore, there is no need to repeat permeation measurements for each separate real-time temperature profile of interest. The same two Constant Temperature measurements can be used to estimate permeation performance for many different temperature cycles - for example, the temperature cycles prescribed by CARB, EPA, and EEC, or the different temperature profiles experienced by separate fuel system components during a vehicle SHED test.
Technical Paper

Modeling the Effect of Substrate Cell Shape on Conversion in Monolith Catalysts

2001-03-05
2001-01-0932
Mass transfer limitations from the bulk gas phase to the surface of the catalyst as well as mass transfer limitations within the washcoat itself have important effects on conversion in washcoated monolith catalysts. These factors depend upon the shape of the channel as well as the loading of washcoat material. This paper outlines a method to describe the washcoat distribution profile for different channel shapes and washcoat loadings. This allows for prediction of effectiveness factors and bulk mass transfer coefficients as a function of cell geometry and washcoat loading for the oxidation of propane. It was found that differences in the diffusion limitations within the washcoat control conversion in the catalyst more than differences in bulk mass transfer rates when comparing different cell shapes. The results show that optimum washcoat loadings exist for the geometry of each cell, and that these optimum loadings are a function of catalyst temperature.
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